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Institut de minéralogie, de physique des matériaux et de cosmochimie

2D Materials: Electronic structure, Devices and Applications

Permanent Personnel

Johan Biscaras, Abhay Shukla


Current PhD Students:

Wenyi Wu, Ali Fakih, Edoardo Sterpetti


Past PhD students

Zhesheng Chen, Emilio Velez, Mohammed Boukhicha, Adrian Balan


Research areas:

Phase transitions in 2D driven by space charge doping and dimensionality

- Superconductivity, insulator-metal transition, charge density waves. These phenomena are directly related to the density of electronic levels at the Fermi level, the strength of electron-phonon coupling in a given material and to dimensionality. Our strategy is to control the density of states through the space charge doping method we have developed, as shown by a recent study on MoS2 in which we induce superconductivity. The promise of this line of research is confirmed by ongoing work on various materials like hi-Tc superconductors, semiconductors and transition metal oxides. Our future work will concentrate on provoking and controlling phase transitions with space charge doping.

- Kosterlitz-Thouless transitions and Topological order. Since space charge doping is active in a layer of the order of a nanometer, the doped area in our samples is always two dimensional. In two dimensions phase transitions are predicted to be of infinite order (Kosterlitz and Thouless), with a disordered high temperature phase and a quasi-ordered low-temperature phase. Space charge doping provides a new way of looking at the insulator-superconductor transition in a single 2D sample by varying carrier density and magnetic field and examining theoretical predictions.


Onset of two-dimensional superconductivity in space charge doped few-layer Molybdenum Disulphide

Space charge induced electrostatic doping of two-dimensional materials: Graphene as a case study

Anharmonic phonons in few-layer MoS2: Raman spectroscopy of ultralow energy compression and shear modes


Devices and Applications

- Transparent Conducting Electrodes (TCE). We propose a new technique of producing TCE’s through space charge doping of large area thin films. The vast majority of TCE’s are deposited on glass substrates. We use the specifity of space charge doping to induce ultra-high carrier density and conductivity in thin films deposited on glass substrates. We have demonstrated this possibility in both layered materials (graphene) and oxides (ZnO).

- Improving optoelectronic device efficiency.  2D materials are poised to introduce major gains in the field of optoelectronics as seen through the example of the simple photoconductor device. Combining layers of different materials with complementary properties can lead to a hybrid sandwich structure with new properties. Associating graphene (charge transport) with a layered semiconductor (light to charge conversion) can lead to a very efficient photoconductor. Instead of the lateral geometry for current transport in standard devices, a vertical geometry in ultra-thin devices can further maximize effective device volume and minimize losses in transport.


A high performance graphene/few-layer InSe photo-detector!divAbstract

Anodic bonded 2D semiconductors: from synthesis to device fabrication

Single step fabrication of N-doped graphene/Si3N4/SiC heterostructures



- Anodic bonding: a method to make few layer 2D films of layered materials (WO 2009 074755)

- Space Charge doping: A method to electrostatically dope 2D thin films (FR 1557308)


Graphene made easy: High quality, large-area samples

Space charge induced electrostatic doping of two-dimensional materials: Graphene as a case study



- Sample fabrication and characterization: Anodic bonding, physical vapour deposition (sputtering, evaporation); micro-Raman, AFM

- Clean room device fabrication

- Low temperature magneto transport

- In-situ space charge doping

- Low temperature Raman spectroscopy

- Low temperature infra-red spectroscopy


Relevant publications

Self-organized metal-semiconductor epitaxial graphene layer on off-axis 4H-SiC(0001)

Atomic oxidation of large area epitaxial graphene on 4H-SiC(0001)

Edge state in epitaxial nanographene on 3C-SiC(100)/Si(100) substrate

Control of the degree of surface graphitization on 3C-SiC(100)/Si(100)

Epitaxial Graphene on 4H-SiC(0001) Grown under Nitrogen Flux: Evidence of Low Nitrogen Doping and High Charge Transfer

Epitaxial graphene on single domain 3C-SiC(100) thin films grown on off-axis Si(100)

High quality 2D crystals made by anodic bonding: a general technique for layered materials

Sharp interface in epitaxial graphene layers on 3C-SiC(100)/Si(100) wafers

Anodic bonded graphene

Epitaxial graphene on cubic SiC(111)/Si(111) substrate



Traductions :

    Spectroscopie : des signatures électroniques et magnétiques mesurées en ultra-haute résolution

    Les spectroscopies dites « de cœur », comme la spectroscopie d’absorption des rayons X (XAS), sont des outils désormais couramment utilisés en sciences des matériaux pour sonder l’environnement d’un élément chimique spécifique. Enregistrées sur une source de rayonnement synchrotron, les signatures spectrales...

    » Lire la suite


    Guillaume Fiquet (Guillaume.Fiquet @

    Directeur de l'institut

    33 +1 44 27 52 17


    Nalini Loret (Nalini.Loret @

    Attachée de direction

    33 +1 44 27 52 17


    Dany Thomas-Emery (danielle.thomas @

    Gestion du personnel

    33 +1 44 27 74 99


    Danielle Raddas (cecile.duflot @

    Gestion financière

    33 +1 44 27 56 82


    Cécile Duflot (cecile.duflot @

    Chargée de communication

    33 +1 44 27 46 86


    Adresse postale

    Institut de minéralogie, de physique des matériaux et de cosmochimie - UMR 7590

    Université Pierre et Marie Curie - 4, place Jussieu - BC 115 - 75252 Paris Cedex 5


    Adresse physique

    Institut de minéralogie, de physique des matériaux et de cosmochimie - UMR 7590

    Université Pierre et Marie Curie - 4, place Jussieu - Tour 23 - Barre 22-23, 4e étage - 75252 Paris Cedex 5


    Adresse de livraison

    Accès : 7 quai Saint Bernard - 75005 Paris, Tour 22.

    Contact : Antonella Intili : Barre 22-23, 4e étage, pièce 420, 33 +1 44 27 25 61



    Fax : 33 +1 44 27 51 52

    L'IMPMC en chiffres

    L'IMPMC compte environ 195 personnes dont :


    • 40 chercheurs CNRS
    • 46 enseignants-chercheurs
    • 19 ITA CNRS
    • 15 ITA non CNRS
    • 50 doctorants
    • 13 post-doctorants
    • 12 bénévoles


     Chiffres : janvier 2016