Aller au contenu Aller au menu Aller à la recherche

accès rapides, services personnalisés
Institut de minéralogie, de physique des matériaux et de cosmochimie

Marie-Anne Arrio


Téléphone : 01 44 27 98 01
Courriel(s) :

Fonction et rattachement

Chargée de recherche CNRS


  • S. F. Jafri, E. S. Koumousi, P. Sainctavit, A. Juhin, V. Schuler, O. Bunau, D. Mitcov, P. Dechambenoit, C. Mathoniere, R. Clerac, E. Otero, P. Ohresser, C. C. D. Moulin, and M. A. Arrio. Large orbital magnetic moment measured in the [TpFe(III)(CN)3]- precursor of photomagnetic molecular prussian blue analogues. Inorg. Chem., 55(14):6980–6987, (2016)
  • J. H. Li, N. Menguy, M. A. Arrio, P. Sainctavit, A. Juhin, Y. Z. Wang, H. T. Chen, O. Bunau, E. Otero, P. Ohresser, and Y. X. Pan. Controlled cobalt doping in the spinel structure of magnetosome magnetite: new evidences from element- and site-specific x-ray magnetic circular dichroism analyses. Journal of the Royal Society Interface, 13(121):20160355, (2016).
  • M. Hunault, V. Vercamer, M. W. Haverkort, M.-A. Arrio, C. Brouder, G. Calas, and A. Juhin. Tracking the signature of low symmetry environments in the xas K pre-edge. Journal of Physics: Conference Series, 712(1):012005, (2016)
  • Y. Prado, N. Daffe, A. Michel, T. Georgelin, N. Yaacoub, J. M. Greneche, F. Choueikani, E. Otero, P. Ohresser, M. A. Arrio, C. Cartier-dit Moulin, P. Sainctavit, B. Fleury, V. Dupuis, L. Lisnard, and J. Fresnais. Enhancing the magnetic anisotropy of maghemite nanoparticles via the surface coordination of molecular complexes. Nature comm., 6:10139 (2015)
  • Betto, D.; Thiyagarajah, N. ; Lau, Y.-C. ; Piamonteze, C; Arrio, M-A; Stamenov, P; Coey, JMD; Rode, K. Site-specific magnetism of half-metallic Mn2RuxGa thin films determined by x-ray absorption spectroscopy. Phys. Rev. B  Vol 91, Issue 9, 094410 (2015)
  • Aghavnian, T.; Moussy, J. -B.; Stanescu, D. ; Belkhou, R; Jedrecy, N; Magnan, H; Ohresser, P ; Arrio, M-A; Sainctavit, P; Barbier, A. Determination of the cation site distribution of the spinel in multiferroic CoFe2O4/BaTiO3 layers by X-ray photoelectron spectroscopy. Journal of Electron Spectroscopy and Related Phenomena, Vol 202, pp 16-21 (2015)
  • Matzen, S ; Moussy, JB ; Wei, P ; Gatel, C ; Cezar, JC ; Arrio, MA ; Sainctavit, P ; Moodera, JS. Structure, magnetic ordering, and spin filtering efficiency of NiFe2O4(111) ultrathin films. Applied Physics Letters 104, 18, 182404 (2014).
  • Prado, Y  ; Arrio, MA ; Volatron, F ; Otero, E; Cartier dit Moulin, C.; Sainctavit, P ; Catala, L ; Mallah, T. Magnetic anisotropy of cyanide-bridged core and core-shell coordination nanoparticles probed by X-ray Magnetic Circular Dichroism. Chemistry-A European Journal, 19, 6685-6694 (2013).
  • Warner, B.; Oberg, J. C.; Gill, T. G. ; El Hallak, F ; Hirjibehedin, CF ; Serri, M ; Heutz, S ; Arrio, M.-A. ; Sainctavit, P ; Mannini, M ; Poneti, G ; Sessoli, R ; Rosa, P. Temperature- and Light-Induced Spin Crossover Observed by X-ray Spectroscopy on Isolated Fe(II) Complexes on Gold. Journal of Physical Chemistry Letters, Vol 4, Iss 9, pp 1546-1552 (2013).
  • Bunau, O.; Arrio, M. -A.; Sainctavit, Ph.; Paulatto, L.; Calandra, M.; Juhin, A.; Marvaud, V.; Cartier dit Moulin, C. Understanding the Photomagnetic Behavior in Copper Octacyanomolybdates. J. Phys. Chem. A, 116, 34, p8678-8683, (2012).
  • Guyodo, Y.; Sainctavit, Ph.; Arrio, M-A; Carvallo, C.; Penn, R. L.; Erbs, J. J.; Forsberg, B. S.; Morin, G.; Maillot, F.; Lagroix, F.; Bonville, P.; Wilhelm, F.; Rogalev, A. X-ray magnetic circular dichroism provides strong evidence for tetrahedral iron in ferrihydrite ; Geochemistry Geophysics Geosystems, 13,  Q06Z44, (2012).
  • Brossard S., Volatron F., Lisnard L., Arrio M-A, Catala L, Mathoniere C., Mallah T., Cartier dit Moulin Ch., Rogalev A., Smekhova A., Sainctavit Ph. Investigation of the photoinduced magnetization of copper octacyanomolybdates nanoparticles by X-ray Magnetic Circular Dichroism; J. Am. Chem. Soc. , 134, 1, p222-228; (2012).
  • P. Sainctavit, C. Cartier dit Moulin, M. Mannini, M.-A. Arrio. X-ray magnetic circular dichroism of single molecule magnets grafted on gold surface. Actualite Chimique, 356-57, 58-61 (2011).
  • S ; Matzen, J.-B. Moussy, R. Mattana, F. Petroff, C. Gatel, B. Warot-Fonrose, J.-C. Cezar, A. Barbier, M.-A. Arrio, Ph. Sainctavit. Restoration of bulk magnetic properties by strain engineering in epitaxial CoFe2O4 (001) ultrathin films. Applied Physics Letters, 99, 5, 052514 (2011).
  • S. Matzen, J.-B. Moussy, R. Mattana, K. Bouzehouane, C. Deranlot, F. Petroff, J.C. Cezar, M.-A. Arrio, Ph. Sainctavit, C. Gatel, B. Warot-Fonrose, Y. Zheng. Epitaxial growth and ferrimagnetic behavior of MnFe2O4(111) ultrathin layers for room-temperature spin filtering. Phys. Rev B, 83, 18, 184402 (2011).
  • M. Mannini, E. Tancini, L. Sorace, Ph. Sainctavit, M.-A. Arrio, Y. Qian, E. Otero, D. Chiappe, L. Margheriti, J.C. Cezar, R. Sessoli, A. Cornia . Spin Structure of Surface-Supported Single-Molecule Magnets from Isomorphous Replacement and X-ray Magnetic Circular Dichroism. Inorganic Chemistry, 50, 7, 2911-2917 (2011).
  • J.-D. Cafun, C. Cartier dit Moulin, G. Fornasieri, M.-A. Arrio, V. Briois, A. Bleuzen. A chemical model of intermediate states implied in the switching properties of CoFe Prussian blue analogues: how a cell parameter lengthening can cause a crystal field parameter increase. New Journal of Chemistry, 35, 10, 2074-2080 (2011).
  • L. Margheriti, D. Chiappe, M. Mannini, P.-E.Car, Ph. Sainctavit, M.-A. Arrio, F. de Mongeot, C. Buatier, J.C. Cezar, F. M. Piras, A. Magnani, E. Otero, A. Caneschi, Andrea, R. Sessoli. X-ray detected magnetic hysteresis of thermally evaporated terbium double-decker oriented films. Advanced Materials, 22, 48, 5488-5493 (2010).
  • M. Mannini, F. Pineider, C. Danieli, F. Totti, L. Sorace, Ph. Sainctavit, M.-A. Arrio, E. Otero, L. Joly, J.C. Cezar, A. Cornia, R. Sessoli. Quantum tunnelling of the magnetization in a monolayer of oriented single-molecule magnets. NATURE, 468, 7322, 417-421 (2010).
  • J.-D. Cafun, G. Champion, M.-A. Arrio, C. Cartier dit Moulin and A. Bleuzen . Photomagnetic CoFe Prussian Blue Analogues: Role of the Cyanide Ions as Active Electron Transfer Bridges Modulated by Cyanide−Alkali Metal Ion Interactions. J. Am. Chem. Soc.,132 (33), 11552–11559 (2010).
  • C. Carvallo, P. Sainctavit, M.-A. Arrio, Y. Guyodo, R. L. Penn, B. Forsberg, A. Rogalev, F. Wilhelm, A. Smekhova, Self-reversal of magnetization in oceanic submarine basalts studied with XMCD, Geophysical Research Letters, VOL. 37, L11306, 5 PP. (2010).
  • A. Bordage, C. Brouder, E. Balan, D. Cabaret, A. Juhin, M.-A. Arrio, Ph. Sainctavit, G. Calas, P. Glatzel . Pieter, Electronic structure and local environment of substitutional V(3+) in grossular garnet Ca(3)Al(2)(SiO(4))(3): K-edge X-ray absorption spectroscopy and first-principles modeling. American Mineralogist, 95, 8-9, 1161-1171 (2010).
  • G. Poneti, M. Mannini, L. Sorace, Ph. Sainctavit, M-A. Arrio, E. Otero, J. Criginski Cezar, And A. Dei . Soft-X-ray-Induced Redox Isomerism in a Cobalt Dioxolene Complex. Angew. Chem. Int. Ed. 49, 11, 1954-1957 (2010).
  • M-A. Arrio, J. Long, Ch. Cartier Dit Moulin, A. Bachschmidt, V. Marvaud, A. Rogalev, C. Mathoniere, F. Wilhelm, And Ph. Sainctavit. Photoinduced magnetization on Mo ion in Copper octacyanomolybdate: an X-ray Magnetic Circular Dichroism investigation. Journal of Physical Chemistry C Volume: 114, Pages: 593-600 (2010)
  • Copie O, Rode K, Mattana R, Bibes M , Cros V, Herranz G, Anane A , Ranchal R , Jacquet E , Bouzehouane K, Arrio MA , Bencok P , Brookes NB , Petroff F, Barthelemy A. Structural and magnetic properties of Co−doped (La, Sr)TiO3 epitaxial thin films probed using X−ray magnetic circular dichroism. Journal of Physics−Condensed Matter Volume: 21 Issue: 40 Article Number: 406001 (2009)
  • M. Mannini, F. Pineider, Ph. Sainctavit, C. Danieli, E. Otero, C. Sciancalepore, A. M. Talarico, Marie-Anne Arrio, A. Cornia, D. Gatteschi, And R. Sessoli. Magnetic Memory Of A Single-Molecule quantum magnet wired to a gold surface. NATURE MATERIALS Volume: 8, Issue: 3, Pages: 194-197 (2009)
  • M. Mannini, F. Pineider, Ph. Sainctavit, L. Joly, A. Fraile-Rodriguez, M.-A. Arrio, Ch. Cartier Dit Moulin, W. Wernsdorfer, A. Cornia, D. Gatteschi, And R. Sessoli. X-Ray Magnetic Circular Dichroism Picks out Single-Molecule Magnets Suitable for Nanodevices. ADVANCED MATERIALS Volume 21, Pages: 167-171 (2009)
  • G. Poneti, M. Mannini, L. Sorace, Ph. Sainctavit, M-A. Arrio, A. Rogalev, F. Wilhelm, And A. Dei. X-ray Absorption Spectroscopy as a Probe of Photo- and Thermally Induced Valence Tautomeric Transition in a 1:1 Cobalt-Dioxolene Complex. Chem. Phys. Chem, Vol 10 , Issue: 12   Pages: 2090-2095 (2009)
  • Mannini M, Pineider F, Sainctavit P, , Ch. Cartier Dit Moulin, M.-A. Arrio, A. Cornia, D. Gatteschi And R. Sessoli. XMCD of a single layer of single molecule magnets. EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS, Volume: 169, Pages: 167-173 (2009)
  • Christian Brouder, Amelie Juhin, Amelie Bordage And Marie−Anne Arrio. Site symmetry and crystal symmetry: a spherical tensor analysis. J. Phys.: Condens. Matter, 20, No 45, Article Number: 455205 (2008)
  • M. Mannini, F. Pineider, Ph. Sainctavit, Ch. Cartier Dit Moulin, M.-A. Arrio, A. Cornia, D. Gatteschi And R. Sessoli. XAS and XMCD investigation of Mn-12 monolayers on gold. Chemistry-A European Journal   Vol. 14, Pages: 7530-7535 (2008).
  • K. Rode, R. Mattana, A. Anane V. Cros, E. Jacquet, J.-P. Contour, F. Petroff And A. Fert, M.-A. Arrio, P. Sainctavit, P. Bencok, F. Wilhlem, N. Brookes, And A. Rogalev. Magnetism of (Zn,Co)O thin films probed by X-ray absorption spectroscopies. APPLIED PHYSICS LETTERS Vol.92, 012509 (2008)
  • Carvallo, C. ; Sainctavit, Ph. ; Arrio, M.-A. ; Menguy, N. ; Wang, Y. ; Ona-Nguema, G. ; Brice-Profeta S. Biogenic vs. abiogenic magnetite nanoparticles: A XMCD study. AMERICAN MINERALOGIST Vol. 93, Pages: 880-885 (2008)
  • Christophe Cartier dit Moulin, Guillaume Champion, Jean-Daniel Cafun, Marie-Anne Arrio, Anne Bleuzen. Structural Rearrangements Induced by Photoexcitation in a RbCoFe Prussian Blue Derivative. Angewandte Chemie International Edition, Volume 46, Issue 8, pp 1287-1289 (2007)
  • Virginie Escax, Guillaume Champion, Marie-Anne Arrio, Michele Zacchigna, Christophe Cartier dit Moulin, Anne Bleuzen. The Co ligand field: a key parameter in photomagnetic CoFe Prussian Blue derivatives. Angewandte Chemie International Edition, Vol 44,  30, p 4798-4801 (2005).
  • Magnetic order in g-Fe2O3 nanoparticles: a XMCD study. S. Brice-Profeta, M.-A. Arrio, E. Tronc, N. Menguy, I. Letard, C. Cartier dit Moulin, M. Noguèse, C. Chanéac, J.-P. Jolivet, Ph. Sainctavit. J. Magnetism and Magnetic Materials 288 (2005) 354–365
  • S. Brice, M.-A. Arrio, E. Tronc, I. Letard, C. Cartier dit Moulin, P. Sainctavit. XMCD investigation of spin disorder in g-Fe2O3 nanoparticles at the Fe L2,3 edges. Physica Scripta, T115, 626 (2005)
  • P. Le Fevre, J. Danger, H. Magnan, D. Chandesris, J. Jupille, S. Bourgeois, M.-A. Arrio, R. Gotter, A. Verdini, and A. Morgante. Stoichiometry-related Auger lineshapes in titanium oxides: Influence of valence-band profile and of Coster-Kronig processes. Phys Rev B 69, 155421, (2004)
  • G. Champion, V. Tangoulis, M.-A. Arrio, P. Sainctavit, F. Villain, R. Sessoli, D. Gatteschi, C. Giorgetti, F. Baudelet, M. Verdaguer, C. Cartier dit Moulin. XMCD for Monitoring Exchange Interactions. The Role of the Gd 4f and 5d Orbitals in Metal-Nitroxyl Nitroxide Magnetic Chains. J. Am. Chem. Soc. , 125, 8371-8376 (2003)
  • R. Moroni, C. Cartier dit Moulin, G. Champion, M.-A. Arrio, P. Sainctavit, M. Verdaguer, D. Gatteschi. “Measurements and Calculations of X-ray Magnetic Circular Dichroism in the Molecular Superparamagnet  Mn12-ac”. Phys. Rev. B 2003, 68, 064407-1-7.
  • G. Champion, M.-A. Arrio, P. Sainctavit, M. Finazzi, F. Villain, C. Mathoniere, Ch. Cartier dit Moulin. Size effect on Local Magnetic Moments in Ferrimagnetic Molecular Complexes : An XMCD Investigation. Monatshefte für Chemie 2003, 134 , 277-284.
  • Cabaret D.,Brouder C.,Arrio M.A.,Sainctavit Ph., Joly Y.,Rogalev A.,Goulon J. Natural linear dichroism in pyrite (FeS2): experiments and calculations. Proc. XAFS 11, Ako (Japon), Journal of Synchrotron Radiation, 2001, 8, 460-462.
  • Galoisy L., Calas G, Arrio M.-A. High resolution XANES spectra of iron in minerals and glasses: structural information from the pre-edge region. CHEM. GEOL., 2001, 174, 307-319.
  • Arrio M.-A, Rossano S., Brouder Ch., Galoisy L., Calas G. Calculation of multipole transition at the Fe K pre-edge through p-d hybridization in the ligand field multiplet model. Europhys. Lett., 51, p454 (2000).
  • Cartier Dit Moulin Ch., Villain F., Bleuzen A., Sainctavit Ph., Lomenech C., Escax V., Baudelet F., Dartyge E., Gallet J.-J., Arrio, M.-A. And Verdaguer M. Photo-Induced Ferrimagnetic Sustems in Prussian Blue Analogues CIxCo4[Fe(CN)6]y (CI=alkali cation). Part II: X-Ray Absorption Spectroscopy of the Metastable State. J. Am. Chem. Soc., 122, p6653 (2000).
  • Rossano S., Brouder Ch., Alouani M., Arrio M.-A. Calculated optical spectra of Ni2+ bearing compounds. Phys. Chem. Minerals, 27 (2000) p170.
  • M.-A. Arrio, A. Scuiller, Ph. Sainctavit, Ch. Cartier Dit Moulin, T. Mallah, M. Verdaguer. Soft X-ray Magnetic Circular Dichroism in Paramagnetic Systems: Element Specific Magnetization of two Heptanuclear CrIIIMII6 High Spin Molecules. J. Am. Chem. Soc., 121, p6414 (1999).
  • Galoisy L., Pelegrin E., Arrio M.-A., Ildephonse Ph.; Calas G, Ghaleb D., Fillet C., Pacaud F. Evidences for 6-coordinated Zr in inactive nuclear waste glasses. J. Am. Ceram. Soc., 82, p2219 (1999).
  • Rivet B., Arrio M.-A., Sainctavit Ph. Multiple Scattering theory applied to XMCD spectra in molecule-based magnets. Properties of Complex Inorganic Solids, 1997, Ed. A. Gonis, pp.461-466 (Plenum Press, New York).
  • Arrio M.-A., Sainctavit Ph., Cartier dit Moulin Ch., Brouder Ch., Mallah T. And Verdaguer M. Soft XMCD in Molecule Based Magnets. Journal de Physique IV, 1997, C2, pp.409-413.
  • M.-A. Arrio, Ph. Sainctavit, Ch. Cartier dit Moulin, T. Mallah, M. Verdaguer, E. Pellegrin, C.T. Chen. Characterization of Chemical Bonds in Bimetallic Cyanides Using X-Ray Absorption Spectroscopy at L2,3 edges. J. Am. Chem. Soc., 118, p6422 (1996).
  • M.-A. Arrio, Ph. Sainctavit, Ch. Cartier dit Moulin, Ch. Brouder, F. de Groot, T. Mallah, M. Verdaguer. Measurement of magnetic moment at the atomic scale in high TC molecular magnets. J. Phys. Chem., 100, 4679 (1996).
  • Ph. Sainctavit, M.A. Arrio, Ch. Brouder. Determination of <Tz> at Cu2+ L2,3 edges, Phys. Rev. B, 52, 12766 (1995).
  • M. Verdaguer, T. Mallah, C. Hélary, F. L'Hermite, Ph. Sainctavit, M.-A. Arrio, D. Babel, F. Baudelet, E. Dartyge, A. Fontaine. K Edge X-Ray Magnetic Circular Dichroism in Molecule-based Magnets. Physica B, 208 (1995).
  • F.M.F. de Groot, M.-A. Arrio, Ph.Sainctavit, Ch. Cartier, C.T. Chen. Distortions of X-Ray absorption spectra measured with fluorescence yield. Physica B, 208 (1995).
  • M.-A. Arrio, Ph.Sainctavit, Ch. Brouder, C. Deudon, XMCD sum rules at Cu2+ L2,3 edges. Physica B, 208, 27 (1995).
  • M.-A. Arrio, Ph.Sainctavit, Ch. Cartier dit Moulin, Ch. Brouder, F.M.F. de Groot, T. Mallah, M. Verdaguer, C.T. Chen. Soft X-ray magnetic circular dichroism in molecular based magnets. Physica B, 208, 775 (1995).
  • F.M.F de Groot, M.A. Arrio, Ph. Sainctavit, Ch. Cartier and C.T Chen. Fluorescence Yield Detection : Why it does not measure the X-ray absorption cross section. Solid State Comm., 92, 991 (1994).
  • Ph. Sainctavit, D. Lefebvre, M.-A. Arrio, Ch. Cartier dit Moulin, J.-P. Kappler, J.-Ph. Schillé, G. Krill, Ch. Brouder, M. Verdaguer. Magnetic Circular Dichroism at High Magnetic Field and Low Temperature. Proc. 7th Int. Conf. X-Ray Absorption Fine Structure, Kobe, Jpn. J. Appl. Phys. 32, 295 (1993)


Chapitre dans des ouvrages

  • Philippe Sainctavit, Sandrine Brice-Profeta, Emilie Gaudry, Isabelle Letard and Marie-Anne Arrio. X-Ray Spectroscopy and Magnetism in Mineralogy. Magnetism and Synchrotron Radiation; Eds E. Beaurepaire, B. Carrière, J.-P. Kappler; Editions de Physique (Mittelwihr 2004).
  • G. Champion, M.-A. Arrio, P. Sainctavit, M. Finazzi, F. Villain, C. Mathoniere, Ch. Cartier dit Moulin. Size effect on local magnetic moments in ferrimagnetic molecular complexes : an XMCD investigation. Molecular Magnets,Recent Highlights, W. Linert et M. Verdaguer Eds., Springer, 2003,pp. 161-168.
  • Sainctavit Ph., Cartier Dit Moulin Ch., Arrio M.-A., Magnetic Measurements at the Atomic Scale in Molecular Magnetic and Paramagnetic Compounds, in Magnetism: Molecules to Materials. Models and Experiments; Eds J.S.Miller and M. Drillon; Wiley-VCH (2001).
  • Ph. Sainctavit, M.-A. Arrio. Ligand Field Multiplet Theory Applied to the Calculation of X-Ray Absorption Spectra. Magnetism and Synchrotron Radiation; Eds E. Beaurepaire, B. Carrière, J.-P. Kappler; Editions de Physique 1997; p74-130.

Cécile Duflot - 17/01/18

Traductions :

    Ionisation des glaces sous les pressions des planètes géantes

    L’eau et l’ammoniac sont des molécules simples très abondantes dans l’Univers. En particulier, ces composés seraient, avec le méthane, les constituants majoritaires des couches internes des planètes géantes glacées (Uranus, Neptune), de satellites (Titan, Ganymède) et d’exoplanètes telles que GJ 436b...

    » Lire la suite


    Guillaume Fiquet (Guillaume.Fiquet @

    Directeur de l'institut

    33 +1 44 27 52 17


    Nalini Loret (Nalini.Loret @

    Attachée de direction

    33 +1 44 27 52 17


    Evancia Mahambou (evancia.mahambou @

    Gestion du personnel

    33 +1 44 27 74 99


    Danielle Raddas (cecile.duflot @

    Gestion financière

    33 +1 44 27 56 82


    Cécile Duflot (cecile.duflot @

    Chargée de communication

    33 +1 44 27 46 86


    Expertise de météorites


    Expertise de matériaux et minéraux


    Stages d'observation pour les 3e et les Seconde : (feriel.skouri @


    Adresse postale

    Institut de minéralogie, de physique des matériaux et de cosmochimie - UMR 7590

    Sorbonne Université - 4, place Jussieu - BC 115 - 75252 Paris Cedex 5


    Adresse physique

    Institut de minéralogie, de physique des matériaux et de cosmochimie - UMR 7590 - Sorbonne Université - 4, place Jussieu - Tour 23 - Barre 22-23, 4e étage - 75252 Paris Cedex 5


    Adresse de livraison

    Accès : 7 quai Saint Bernard - 75005 Paris, Tour 22.

    Contact : Antonella Intili : Barre 22-23, 4e étage, pièce 420, 33 +1 44 27 25 61



    Fax : 33 +1 44 27 51 52

    L'IMPMC en chiffres

    L'IMPMC compte environ 195 personnes dont :


    • 40 chercheurs CNRS
    • 46 enseignants-chercheurs
    • 19 ITA CNRS
    • 15 ITA non CNRS
    • 50 doctorants
    • 13 post-doctorants
    • 12 bénévoles


     Chiffres : janvier 2016